Section 1 - Identification of The Material and Supplier
Chemical nature: Blend of liquid hydrocarbons and other minor ingredients presented as an aerosol
Trade Name: XDP 905 Spray
Product Use: Industrial metal working fluid
Creation Date: May 2017
This version issued: August 2017 and is valid for 5 years from this date
Poisons Information Centre: Phone 13 1126 from anywhere in Australia
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Not hazardous according to the criteria of SWA.
Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.
SUSMP Classification: None allocated.
ADG Classification: Class 2.1: Flammable gases. UN Number: 1950, AEROSOLS
GHS Signal word: WARNING
Flammable aerosols Category 2
Gases under pressure - Compressed gas
HAZARD STATEMENT:
H223: Flammable aerosol
H280: Contains gas under pressure; may explode if heated.
PREVENTION
P102: Keep out of reach of children.
P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P211: Do not spray on an open flame or other ignition source.
P251: Pressurized container: Do not pierce or burn, even after use.
P261: Avoid breathing fumes, mists, vapours or spray.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well ventilated area.
P281: Use personal protective equipment as required.
RESPONSE
P312: Call a POISON CENTRE or doctor if you feel unwell.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water. P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P372: Explosion risk in case of fire.
P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Water fog or fine spray is the preferred medium for large fires.
STORAGE
P403: Store in a well-ventilated place.
P410+P412: Store below 30°C, protect from direct sunlight and do not expose to temperatures exceeding 50°C.
DISPOSAL
P501: Dispose of small quantities and empty containers by wrapping with paper and putting in garbage. For larger quantities, if recycling or reclaiming is not possible, use a commercial waste disposal service.
Phone: 1800 633 448 (office hours) Fax: 03 5571 1944 sales@excision.com.au
Blend of liquid hydrocarbons and other minor ingredients presented as an aerosol.
XDP905 Spray
Industrial metal working fluid.
May, 2017
August, 2017 and is valid for 5 years from this date.
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Issued by: Excision Pty Ltd
Phone: 1800 633 448 (office hours)
Emergency Overview
Physical Description & Colour: Clear colourless liquid dispensed as an aerosol. Odour: Mild characteristic odour.
Major Health Hazards: no significant risk factors have been found for this product.
Section 3 - Composition/Information on Ingredients
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
Issued by: Excision Pty Ltd
Phone: 1800 633 448 (office hours)
Not available Not available
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Gently blot away excess liquid. Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until chemical is removed.
Eye Contact: Quickly and gently blot material from eyes. Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses.
Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen deficient (or both), fire gases. There is a moderate risk of an explosion from this product if commercial quantities are involved in a fire. Firefighters should take care and appropriate precautions. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids. Vapours from this product are heavier than air and may accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash back considerable distances.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures. Extinguishing Media: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Water fog or fine spray is the preferred medium for large fires. Try to contain spills, minimise spillage entering drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is a danger of a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal protective equipment is full fire kit and breathing apparatus. Cool closed, undamaged containers exposed to fire with water spray.
Flash point:
Upper Flammability Limit:
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: XDP905 Spray Page: 2 of 6 This version issued: August, 2017
Alkanes, C3-4
1,3,4-Thiadiazole, 2,5-bis(tert-nonyldithio)- 9-Octadecen-1-amine, (Z)-
9-Octadecenoic acid, methyl ester, (Z)- Alkoxylated long-chain alkanol borate
Amines, C12-14-tert-alkyl
Distillates, petroleum, hydrotreated light paraffinic Phosphoric acid, bis(2-ethylhexyl) ester
alkyl phosphonate
Other non hazardous ingredients
68475-59-2 89347-09-1 112-90-3 112-62-9 Confidential 68955-53-3 64742-55-8 298-07-7 Confidential secret
no data <10 <10
0
<10
<10
>60
<10
<10
to 100
not set not set not set not set not set not set not set not set not set not set
not set not set not set not set not set not set not set not set not set not set
Section 6 - Accidental Release Measures
Product Name: XDP905 Spray Page: 3 of 6 This version issued: August, 2017
Accidental release: This product is sold in small packages, and the accidental release from one of these is not usually a cause for concern. For minor spills, clean up, rinsing to sewer and put empty container in garbage. Although no special protective clothing is normally necessary because of occasional minor contact with this product, it is good practice to wear impermeable gloves when handling chemical products. In the event of a major spill, prevent spillage from entering drains or water courses and call emergency services.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.
Storage: Store in a cool (below 30°C), well ventilated area. Protect from direct sunlight. Make sure that surrounding electrical devices and switches are suitable. Check containers and valves periodically for leaks. If you keep more than 25kg of flammable gases, you are probably required to license the premises or notify your Dangerous Goods authority. If you have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify your obligations. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501
set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
Exposure limits have not been established by SWA for any of the significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a fan is suggested.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable impervious elbow-length gloves and facial protection when handling this product. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above.
Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Odour:
Boiling Point: Freezing/Melting Point: Volatiles:
Vapour Pressure: Vapour Density: Specific Gravity: Water Solubility: pH:
Volatility:
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Issued by: Excision Pty Ltd
Phone: 1800 633 448 (office hours)
Clear colourless liquid dispensed as an aerosol. Mild characteristic odour.
Not available.
No specific data. Liquid at normal temperatures. No data.
No data.
No data.
Typically 0.90 at 20°C Insoluble.
No data.
No data.
Lower Flammability Limit: Autoignition temperature: Flammability Class:
Not available
>210°C (liquid phase). No data.
Section 10 - Stability and Reactivity
Product Name: XDP905 Spray Page: 4 of 6 This version issued: August, 2017
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Store below 30°C, protect from direct sunlight and do not expose to temperatures exceeding 50°C. Containers should be kept dry. Keep containers and surrounding areas well ventilated. Keep away from sources of sparks or ignition. Any electrical equipment in the area of this product should be flame proofed. Incompatibilities: strong oxidising agents.
Fire Decomposition: Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also formed. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.
Corrosion/Irritancy:
-
Eye: this material has been classified as not corrosive or irritating to eyes.
-
Skin: this material has been classified as not corrosive or irritating to skin.
Classification of Hazardous Ingredients
Ingredient
Alkanes, C3-4
-
Gas under pressure
-
Flammable gas - category 1
Petroleum Solvent
Risk Phrases
No risk phrases at concentrations found in this product
No risk phrases at concentrations found in this product
Potential Health Effects
Inhalation:
Short Term Exposure: High vapour pressures may cause drowsiness and dizziness. In addition product is unlikely
to cause any discomfort or irritation. Intentional misuse by deliberately concentrating and inhaling contents of aerosol containers can be harmful or fatal.
Long Term Exposure: Vapours may cause drowsiness and dizziness.
Skin Contact:
Short Term Exposure: Major health effect from this product is misuse of the aerosol function. If sprayed
continuously on skin or in eyes, it can cause frostbite. Contact with skin will result in severe irritation. Corrosive to skin - may cause skin burns.
Long Term Exposure: Repeated exposure may cause skin dryness or cracking.
Eye Contact:
Short Term Exposure: If sprayed directly in the eye, this product will irritate. If spraying is prolonged, it may cause
damage through frostbite. A severe eye irritant. Corrosive to eyes: contact can cause corneal burns. Contamination of eyes can result in permanent injury.
Long Term Exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort.
Long Term Exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Issued by: Excision Pty Ltd
Phone: 1800 633 448 (office hours)
Odour Threshold: Evaporation Rate:
Coeff Oil/water Distribution: Autoignition temp:
No data.
No data.
No data
242°C (liquid phase).
Product Name: XDP905 Spray Page: 5 of 6 This version issued: August, 2017
Section 12 - Ecological Information
Insufficient data to be sure of status.
Acute aquatic hazard: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): >100 mg/L
Long-term aquatic hazard: This material has been classified as non-hazardous. Non-rapidly or rapidly degradable substance for which there are adequate chronic toxicity data available OR in the absence of chronic toxicity data, Acute toxicity estimate (based on ingredients): >100 mg/L, where the substance is not rapidly degradable and/or BCF < 500 and/or log Kow < 4.
Ecotoxicity: No information available.
Persistence and degradability: No information available. Bioaccumulative potential: No information available. Mobility: No information available.
Section 13 - Disposal Considerations
Disposal: Dispose of small quantities and empty containers by wrapping with paper and putting in garbage. For larger quantities, if recycling or reclaiming is not possible, use a commercial waste disposal service. Do not puncture or incinerate aerosol cans, even when empty.
Section 14 - Transport Information
Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.
UN Number: 1950, AEROSOLS
Hazchem Code: 2YE
Special Provisions: 63, 190, 277, 327, 344, 381
Limited quantities: ADG 7 specifies a Limited Quantity value of 1000mL for this class of product. Dangerous Goods Class: Class 2.1: Flammable gases.
Packing Group: Not set
Packing Instruction: P207, LP200
Class 2.1 Flammable gases shall not be loaded in the same vehicle or packed in the same freight container with Classes 1 (Explosives), 3 (Flammable Liquids) (where both flammable liquids and flammable gases are in bulk), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), and 7 (Radioactive Substances). They may however be loaded in the same vehicle or packed in the same freight container with Classes 2.2 (Non-flammable Non-Toxic gases), 3 (Flammable liquids except where both flammable liquids and flammable gases are in bulk), 6 (Toxic Substances), 8 (Corrosive Substances) 9 (Miscellaneous dangerous goods), Foodstuffs and foodstuff empties.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations. The following ingredient: Petroleum solvent (as liquid hydrocarbon), is mentioned in the SUSMP.
Section 16 - Other Information
This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code AICS
SWA
CAS number Hazchem Code
IARC
NOS
NTP SUSMP
UN Number
Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition) Australian Inventory of Chemical Substances
Safe Work Australia, formerly ASCC and NOHSC
Chemical Abstracts Service Registry Number
Emergency action code of numbers and letters that provide information to emergency services especially firefighters
International Agency for Research on Cancer
Not otherwise specified
National Toxicology Program (USA)
Standard for the Uniform Scheduling of Medicines & Poisons United Nations Number
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Issued by: Excision Pty Ltd
Phone: 1800 633 448 (office hours)
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Product Name: XDP905 Spray Page: 6 of 6 This version issued: August, 2017
THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous Chemicals - Code of Practice” (Feb 2016)
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