Section 1 - Identification of The Material and Supplier
Chemical nature: Blend of ingredients in a liquid hydrocarbon solvent
Trade Name: Metalium XDP 1000
Product Use: Metal working coolant and lubricant
Creation Date: October, 2014
This version issued: February, 2017
Poisons Information Centre: Phone 13 1126 from anywhere in Australia
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: N, Dangerous to the environment. Not classified as hazardous according to the criteria of SWA.
Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria.
SUSMP Classification: None allocated.
ADG Classification: None allocated. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria.
UN Number: None allocated
GHS Signal word: NONE. Not hazardous. HAZARD STATEMENT:
AUH066: Repeated exposure may cause skin dryness or cracking.
H402: Harmful to aquatic life.
PREVENTION
P262: Do not get in eyes, on skin, or on clothing.
P273: Avoid release to the environment.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P352: Wash with plenty of soap and water.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.
STORAGE
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.
DISPOSAL
P501: If they can not be recycled, dispose of contents to an approved waste disposal plant and containers to landfill (see Section 13 of this SDS).
Emergency Overview
Physical Description & Colour: Yellow-brown liquid.
Odour: No data re odour.
Major Health Hazards: repeated exposure may cause skin dryness or cracking.
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
O-phenyl phenol Diethanolamine 2-(2-butoxyethoxy) ethanol Other non hazardous ingredients
90-43-7 111-42-2 112-34-5 secret
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Section 3 - Composition/Information on Ingredients
Distillates (petroleum), solvent-dewaxed heavy paraffinic set
64742-65-0
<5
<1
<1
to 100
>60
not set 13
not set not set
not set not
not set not set not set not set
Flash point:
Upper Flammability Limit: Lower Flammability Limit: Autoignition temperature: Flammability Class:
180°C
No data.
No data.
No data.
Not flammable (GHS); C2 combustible (AS 1940)
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until chemical is removed.
Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses.
Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen deficient (or both), fire gases. There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures. Extinguishing Media: In case of fire, use carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Product Name: Metalium XDP 1000 Page: 3 of 5 This version issued: February, 2017
Storage: Store packages of this product in a cool place. Make sure that containers of this product are kept tightly closed. Keep containers dry and away from water. Keep containers of this product in a well ventilated area. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check packaging - there may be further storage instructions on the label.
Section 6 - Accidental Release Measures
Accidental release: Minor spills do not normally need any special cleanup measures. In the event of a major spill, prevent spillage from entering drains or water courses. As a minimum, wear overalls, goggles and gloves. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. This material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Issued by: Excision Pty Ltd
Phone: 1800 633 448 (office hours)
Product Name: Metalium XDP 1000 Page: 2 of 5 This version issued: February, 2017
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501
set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
Diethanolamine 13 not set
No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a fan is suggested.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable impervious elbow-length gloves and facial protection when handling this product. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above.
Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.
Section 9 - Physical and Chemical Properties:
PhysicalDescription&colour: Odour:
Boiling Point: Freezing/Melting Point: Volatiles:
Vapour Pressure: Vapour Density: Specific Gravity: Water Solubility: pH:
Volatility:
Odour Threshold: Evaporation Rate:
Coeff Oil/water Distribution: Viscosity:
Autoignition temp:
Yellow-brownliquid.
No data re odour.
Not available.
No specific data. Liquid at normal temperatures. No data.
Negligible at normal ambient temperatures. No data.
0.89
Miscible.
8-9 (as supplied)
Negligible at normal ambient temperatures. No data.
No data.
No data
39.7 cSt (temperature not stated)
No data.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30°C. Keep containers tightly closed. Containers should be kept dry. Keep containers and surrounding areas well ventilated.
Incompatibilities: oxidising agents.
Fire Decomposition: Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also formed. May form nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Issued by: Excision Pty Ltd
Phone: 1800 633 448 (office hours)
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Issued by: Excision Pty Ltd
Phone: 1800 633 448 (office hours)
Product Name: Metalium XDP 1000 Page: 4 of 5 This version issued: February, 2017
Polymerisation: This product will not undergo polymerisation reactions. Section 11 - Toxicological Information
Toxicity: PARAFFINIC DISTILLATE, HEAVY, SOLVENT-DEWAXED (SEVERE)
The materials included in the Lubricating Base Oils category are related from both process and physical-chemical perspectives; The potential toxicity of a specific distillate base oil is inversely related to the severity or extent of processing the oil has undergone, since: The adverse effects of these materials are associated with undesirable components, and The levels of the undesirable components are inversely related to the degree of processing; Distillate base oils receiving the same degree or extent of processing will have similar toxicities; The potential toxicity of residual base oils is independent of the degree of processing the oil receives.
The reproductive and developmental toxicity of the distillate base oils is inversely related to the degree of processing. Unrefined & mildly refined distillate base oils contain the highest levels of undesirable components, have the largest variation of hydrocarbon molecules and have shown the highest potential carcinogenic and mutagenic activities. Highly and severely refined distillate base oils are produced from unrefined and mildly refined oils by removing or transforming undesirable components.
O-PHENYLPHENOL, DIETHANOLAMINE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.
Potential Health Effects
Inhalation:
Short Term Exposure: Available data indicates that this product is not harmful. In addition product is unlikely to cause any discomfort or irritation.
Long Term Exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short Term Exposure: Available data indicates that this product is not harmful. It should present no hazards in normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort. Long Term Exposure: Repeated exposure may cause skin dryness or cracking.
Eye Contact:
Short Term Exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild transient discomfort.
Long Term Exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort.
Long Term Exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: Distillates (petroleum), Solvent-dewaxed Heavy Paraffinic is classified by SWA as a Class 2 Carcinogen, likely
to be carcinogenic to humans.
See the SWA website for further details. A web address has not been provided as addresses frequently change. NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: O-phenyl Phenol is Class 3 - unclassifiable as to carcinogenicity to humans.
Diethanolamine is classed 2b IARC - possibly carcinogenic to humans.
See the IARC website for further details. A web address has not been provided as addresses frequently change.
Section 12 - Ecological Information
This product is harmful to aquatic organisms. No further details are available.
Section 13 - Disposal Considerations
Disposal: This product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some
ADG Code AICS
SWA
CAS number Hazchem Code
IARC
NOS
NTP R-Phrase SUSMP
UN Number
Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition) Australian Inventory of Chemical Substances
Safe Work Australia, formerly ASCC and NOHSC
Chemical Abstracts Service Registry Number
Emergency action code of numbers and letters that provide information to emergency services especially firefighters
International Agency for Research on Cancer
Not otherwise specified
National Toxicology Program (USA)
Risk Phrase
Standard for the Uniform Scheduling of Medicines & Poisons United Nations Number
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous Chemicals - Code of Practice” (Feb 2016)
Copyright © Kilford & Kilford Pty Ltd, February, 2017.
http://www.kilford.com.au/ Phone (02)9251 4532
Product Name: Metalium XDP 1000 Page: 5 of 5 This version issued: February, 2017
other means. If neither of these options is suitable in-house, consider controlled incineration, or contact a specialist waste disposal company.
Section 14 - Transport Information
UN Number: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special transport conditions are necessary unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredient: Distillates (petroleum), solvent-dewaxed heavy paraffinic (a liquid hydrocarbon), is mentioned in the SUSMP.
Section 16 - Other Information
This SDS contains only safety-related information. For other data see product literature. Acronyms:
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